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Manufacturer supply high quality 3-(1-ADAMANTYL)-4-METHOXYBENZENEBORONIC ACID 459423-32-6 with GMP standards
- Molecular Formula: C17H23BO3
- Molecular Weight: 286.179
- Vapor Pressure: 7.89E-10mmHg at 25°C
- Melting Point: 239-242
- Refractive Index: 1.583
- Boiling Point: 475.008 °C at 760 mmHg
- PKA: 8.94±0.10(Predicted)
- Flash Point: 241.076 °C
- PSA： 49.69000
- Density: 1.2 g/cm3
- LogP: 1.84280
3-(1-ADAMANTYL)-4-METHOXYBENZENEBORONIC ACID(Cas 459423-32-6) Usage
InChI:InChI=1/C17H23BO3/c1-21-16-3-2-14(18(19)20)7-15(16)17-8-11-4-12(9-17)6-13(5-11)10-17/h2-3,7,11-13,19-20H,4-6,8-10H2,1H3
459423-32-6 Relevant articles
Synthesis of 3-(1-adamantyl)-4-methoxyphenylboric acid
Tribulovich,Garabadzhiu,Kalvins
, p. 868 - 869 (2011/01/10)
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PROCESS FOR PREPARATION OF 6-[3-(1-ADMANTYL)-4-METHOXYPHENYL]-2-NAPHTOIC ACID.
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Page/Page column 3-4, (2010/07/04)
A process for preparation of 6-[3-(1-ada...
METHOD FOR PREPARTION OF SUBSTITUTED ADAMANTYLARYMAGNESIUM HALIDES
-
Page/Page column 3, (2010/05/13)
The present invention concerns fine orga...
NOVEL THERAPEUTIC AGENTS FOR THE TREATMENT OF CANCER, METABOLIC DISEASES AND SKIN DISORDERS
-
Page/Page column 51, (2008/06/13)
The present invention is directed to nov...
459423-32-6 Process route
-
-
5419-55-6
Triisopropyl borate
-
-
459423-32-6
3-(1-adamantyl)-4-methoxyphenylboronic acid
Conditions
| Conditions | Yield |
|---|---|
|
2-(1-adamantyl)-4-bromoanisole;
With
n-butyllithium;
In
tetrahydrofuran;
at -75 - -70 ℃;
for 1h;
Triisopropyl borate;
In
tetrahydrofuran;
at -70 - 20 ℃;
With
hydrogenchloride; water;
In
tetrahydrofuran;
at 20 ℃;
|
94.8%
|
-
-
104224-63-7
2-(1-adamantyl)-4-bromoanisole
-
-
459423-32-6
3-(1-adamantyl)-4-methoxyphenylboronic acid
Conditions
| Conditions | Yield |
|---|---|
|
2-(1-adamantyl)-4-bromoanisole;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 ℃;
for 0.0833333h;
With
triethyl borate;
In
tetrahydrofuran; hexane;
at -78 ℃;
for 0.5h;
With
hydrogenchloride;
In
tetrahydrofuran; hexane; water;
at 20 ℃;
|
12%
|
|
2-(1-adamantyl)-4-bromoanisole;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 ℃;
for 0.0833333h;
With
triethyl borate;
In
tetrahydrofuran; hexane; water;
at -78 ℃;
for 0.5h;
With
hydrogenchloride;
In
tetrahydrofuran; hexane; water;
|
12%
|
|
2-(1-adamantyl)-4-bromoanisole;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 ℃;
for 1.16667h;
With
Triisopropyl borate;
In
tetrahydrofuran; hexane;
at -78 - 20 ℃;
for 17h;
With
hydrogenchloride; water;
In
tetrahydrofuran; hexane;
at 0 ℃;
for 0.25h;
|
459423-32-6 Upstream products
-
104224-63-7
2-(1-adamantyl)-4-bromoanisole
-
5419-55-6
Triisopropyl borate
-
121-43-7
Trimethyl borate
459423-32-6 Downstream products
-
106685-41-0
6-(3-adamantan-1-yl-4-methoxyphenyl)naphthalene-2-carboxylic acid methyl ester
-
106685-40-9
adapalene
-
1036766-56-9
2-(3-adamantan-1-yl-4-methoxyphenyl)-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane
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