What is the Tetraphenylporphyrin?

Tetraphenylporphyrin is purple glistening crystalline powder, while it's Molecular Formula is C44H30N4. purple glistening crystalline powder

What is the CAS number for Tetraphenylporphyrin?

The CAS number of Tetraphenylporphyrin is 917-23-7.

What is Tetraphenylporphyrin (917-23-7) used for?

Tetraphenylporphyrin (TPP) is a synthetic porphyrin derivative widely used in supramolecular chemistry, photophysical studies, and as a model for biological systems. It serves as a key building block in self-assembled nanostructures, such as oligo-phenylene-ethynylene (OPE) wires, due to its strong p-conjugation and ability to form stable complexes via hydrogen bonding. TPP is also employed in the synthesis of metalloporphyrin complexes, including alkyl(aryl)iron(III) derivatives, where it acts as a ligand to study metal-carbon bonds and spin delocalization. Additionally, its derivatives are utilized in spectroscopic investigations, such as EPR studies of heme-thiolate proteins, to probe hydrogen bonding effects on electronic structure. TPP's versatility arises from its rigid macrocyclic framework, tunable substituents, and photochemical stability, making it valuable in materials science and bioinorganic research.InChI:InChI=1/C44H30N4/c1-5-13-29(14-6-1)38-27-37-26-35-22-21-33(45-35)25-34-23-24-36(46-34)28-39-40(30-15-7-2-8-16-30)41(31-17-9-3-10-18-31)44(48-39)42(43(38)47-37)32-19-11-4-12-20-32/h1-28,45,48H/b33-25-,34-25-,35-26-,36-28-,37-26-,39-28-,43-42-,44-42-

What is the Tetraphenylporphyrin?

Tetraphenylporphyrin is purple glistening crystalline powder, while it's Molecular Formula is C44H30N4. purple glistening crystalline powder

What is the CAS number for Tetraphenylporphyrin?

The CAS number of Tetraphenylporphyrin is 917-23-7.

What is Tetraphenylporphyrin (917-23-7) used for?

Tetraphenylporphyrin (TPP) is a synthetic porphyrin derivative widely used in supramolecular chemistry, photophysical studies, and as a model for biological systems. It serves as a key building block in self-assembled nanostructures, such as oligo-phenylene-ethynylene (OPE) wires, due to its strong π-conjugation and ability to form stable complexes via hydrogen bonding. TPP is also employed in the synthesis of metalloporphyrin complexes, including alkyl(aryl)iron(III) derivatives, where it acts as a ligand to study metal-carbon bonds and spin delocalization. Additionally, its derivatives are utilized in spectroscopic investigations, such as EPR studies of heme-thiolate proteins, to probe hydrogen bonding effects on electronic structure. TPP's versatility arises from its rigid macrocyclic framework, tunable substituents, and photochemical stability, making it valuable in materials science and bioinorganic research.InChI:InChI=1/C44H30N4/c1-5-13-29(14-6-1)38-27-37-26-35-22-21-33(45-35)25-34-23-24-36(46-34)28-39-40(30-15-7-2-8-16-30)41(31-17-9-3-10-18-31)44(48-39)42(43(38)47-37)32-19-11-4-12-20-32/h1-28,45,48H/b33-25-,34-25-,35-26-,36-28-,37-26-,39-28-,43-42-,44-42-

Cost-effective and customizable Tetraphenylporphyrin 917-23-7 for sale

Pharmaceutical

Current location:Home > Pharmaceutical

Tetraphenylporphyrin

CAS No.: 917-23-7
Purity: 99%

Cost-effective and customizable Tetraphenylporphyrin 917-23-7 for sale

Molecular Formula: C44H30N4
Molecular Weight: 614.749
Appearance/Colour: purple glistening crystalline powder
Melting Point: 300 °C
Refractive Index: 1.702
Boiling Point: 648.45°C (rough estimate)
PSA： 56.30000
Density: 1.22 g/cm³
LogP: 6.86620

Tetraphenylporphyrin(Cas 917-23-7) Usage

Purification Methods

Purify TPP by chromatography on neutral (Grade I) alumina, and recrystallisation from CH2Cl2/MeOH or *C6H6. It forms complexes with metals. [Yamashita et al. J Phys Chem 91 3055 1987, Beilstein 26 III/IV 1958.]

InChI:InChI=1/C44H30N4/c1-5-13-29(14-6-1)38-27-37-26-35-22-21-33(45-35)25-34-23-24-36(46-34)28-39-40(30-15-7-2-8-16-30)41(31-17-9-3-10-18-31)44(48-39)42(43(38)47-37)32-19-11-4-12-20-32/h1-28,45,48H/b33-25-,34-25-,35-26-,36-28-,37-26-,39-28-,43-42-,44-42-

917-23-7 Relevant articles

Physicochemical Basis for the Creation of Liquid-Phase Sensor Materials Based on Tetraaryldithiaporphyrins

Ivanova, Yu. B.,Kiselev, A. N.,Pukhovskaya, S. G.,Syrbu, S. A.

, p. 231 - 240 (2022/03/18)

Abstract: Basic properties of 5,10,15,20...

Method for synthesizing tetraphenylporphyrin by using return pipe type reactor

-

Paragraph 0032-0036; 0038-0042; 0044-0048; 0050-0054, (2021/02/06)

The invention discloses a method for syn...

Tetraphenylporphyrin covalent functionalized titanium disulfide nonlinear nanometer hybrid material and preparation thereof

-

Paragraph 0041-0044, (2021/12/07)

The invention relates to a tetraphenylpo...

The construction of C(sp3)–O bond via copper porphyrin catalyzed cross-dehydrogenative coupling reaction: Substituent and electronic effect of the catalysts

Wang, Feng-Hua,Liu, Zheng-Yan,Yang, Shuang,Shi, Lei,Lin, Dong-Zi,Liu, Hai-Yang,Yuan, Gao-Qing

supporting information, p. 2053 - 2062 (2021/05/26)

The push-pull electronic and steric effe...

917-23-7 Process route

: 1073560-75-4
5,5'-bis(hydroxyphenylmethyl)bipyrrole

: 107798-98-1
5-phenyldipyrromethane

: 917-23-7,20998-75-8
5,15,10,20-tetraphenylporphyrin

: 100-52-7
benzaldehyde

: 5,10,15,20-Triphenylcorrole

Conditions

Conditions	Yield
With dysprosium(III) trifluoromethanesulfonate; at 20 ℃; Reagent/catalyst; Solvent; Concentration; Time; Reactivity;	9.8 %Spectr. 5.4 %Spectr. 4 %Chromat.

: 10087-64-6
2,2'-bipyrrole

: 250695-28-4
1,9-bis-benzoyl-5-phenyldipyrromethane

: meso-hexaphenyl[34]octaphyrin(1.1.1.0.1.1.1.0)

: 917-23-7,20998-75-8
5,15,10,20-tetraphenylporphyrin

: 100-52-7
benzaldehyde

Conditions

Conditions	Yield
With ytterbium(III) triflate; at 20 ℃; Reagent/catalyst; Solvent; Concentration; Reactivity;	6.7 %Spectr. 1.8 %Spectr. 18 %Chromat.

917-23-7 Upstream products

109-97-7
pyrrole
100-52-7
benzaldehyde
872-85-5
pyridine-4-carbaldehyde
4397-53-9
p-benzyloxybenzaldehyde

917-23-7 Downstream products

2669-65-0
meso-tetraphenylchlorin
80612-44-8
C₄₆H₃₂N₄O
90731-31-0
(5Z,10Z,14Z,19Z)-5,10,15,20-Tetraphenyl-porphyrin; compound with 4-nitro-phenol
80612-45-9
N,N'-ethoxymethylene-meso-tetraphenylporphyrin